Oxide materials at the two-dimensional limit

Foreword -- Preface -- Contents -- Contributors -- 1 Structure Concepts in Two-Dimensional Oxide Materials -- Abstract -- 1.1 Introduction -- 1.2 Structure Elements of 2-D Oxide Systems on Metal Surfaces -- 1.2.1 Planar Oxide Monolayers -- 1.2.2 Oxide Bilayer and Trilayer Structures -- 1.2.3 Complex...

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Weitere Verfasser: Netzer, Falko P. (HerausgeberIn), Fortunelli, Alessandro (HerausgeberIn)
Format: UnknownFormat
Sprache:eng
Veröffentlicht: Cham Springer 2016
Schriftenreihe:Springer series in materials science volume 234
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Zusammenfassung:Foreword -- Preface -- Contents -- Contributors -- 1 Structure Concepts in Two-Dimensional Oxide Materials -- Abstract -- 1.1 Introduction -- 1.2 Structure Elements of 2-D Oxide Systems on Metal Surfaces -- 1.2.1 Planar Oxide Monolayers -- 1.2.2 Oxide Bilayer and Trilayer Structures -- 1.2.3 Complex Binary Oxide Structures -- 1.3 Reactive Interfaces-Ternary Oxides: Increasing the Complexity -- 1.4 Finite Size Effects -- 1.5 Interface Chemistry -- 1.6 Surface Phase Diagrams -- 1.7 Pattern Formation -- 1.8 Synopsis -- Acknowledgement -- References
2 Atomistic and Electronic Structure Methods for Nanostructured Oxide Interfaces -- Abstract -- 2.1 Structure Prediction Methods -- 2.2 Total Energy Methods -- 2.2.1 Density-Functional Theory (DFT) -- 2.2.2 Beyond DFT -- 2.2.3 The Promising Field of Multi-component Oxides -- 2.2.4 Practicalities -- 2.3 Electronic States -- 2.3.1 Electronic Ground State (Occupied Orbitals) -- 2.3.2 Electronic Transport Properties -- 2.3.3 Electronic Excited States (Unoccupied or Virtual Orbitals) -- 2.4 Nanoscale Amorphous Oxide Interfaces -- 2.5 Concluding Remarks -- Acknowledgments -- References
3 Role of Structural Flexibility on the Physical and Chemical Properties of Metal-Supported Oxide Ultrathin Films -- Abstract -- 3.1 Introduction -- 3.2 Polaronic Distortion as Response to the Formation of Charged Adsorbates -- 3.3 Electrostatic Origin of Rumpling in Supported Oxide Thin Films -- 3.4 From Structural Flexibility to Chemical Reactivity of Two-Dimensional Oxides -- 3.5 Spontaneous Incorporation of Adsorbed Atoms on Ultrathin Films -- 3.6 Conclusions -- Acknowledgments -- References -- 4 Reducible Oxides as Ultrathin Epitaxial Films -- Abstract -- 4.1 Introduction
4.2 Cerium Oxide Two-Dimensional Films -- 4.3 Titanium Oxide Two-Dimensional Films -- 4.4 Two-Dimensional Films of Other Reducible Oxides -- 4.4.1 Transition Metal Oxide Two-Dimensional Films -- 4.4.2 Rare Earth Oxide Two-Dimensional Films -- 4.5 Conclusions -- Acknowledgements -- References -- 5 Ultrathin Oxide Films on Au(111) Substrates -- Abstract -- 5.1 Introduction -- 5.2 Preparation and Characterization Methods -- 5.2.1 Thin Film Growth -- 5.2.2 Thin Film Characterization -- 5.3 Structural Features of the Oxide Films -- 5.3.1 The Au(111) Substrate Reconstruction
5.3.2 Structure of the Oxide Films -- 5.3.3 Structural Transitions of the Oxide Films -- 5.3.3.1 Stoichiometry-Driven Structural Transitions -- 5.3.3.2 Lattice Mismatch-Driven Structural Transition -- 5.4 Interactions Between the Film and the Substrate -- 5.5 Properties and Potential Applications -- 5.6 Conclusions and Perspectives -- References -- 6 Phonons in Thin Oxide Films -- Abstract -- 6.1 Introduction -- 6.2 Power and Limits of Dielectric Theory -- 6.3 Brief Resume of Selection Rules for Vibrational Spectroscopy -- 6.4 MeO Oxides Thin Films -- 6.4.1 MnO -- 6.4.2 MgO -- 6.4.3 NiO
Beschreibung:xvii, 389 Seiten
Illustrationen, Diagramme
ISBN:9783319283302
978-3-319-28330-2