Bio-sourced adsorbing poly(2-oxazoline)s mimicking mussel glue proteins for antifouling applications

Dissertation, Universität Potsdam, 2022

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Bibliographische Detailangaben
1. Verfasser:	Lüdecke, Nils (VerfasserIn)
Körperschaft:	Universität Potsdam (Grad-verleihende Institution)
Weitere Verfasser:	Schlaad, Helmut (AkademischeR BetreuerIn), Laschewsky, André (AkademischeR BetreuerIn), Schacher, Felix (AkademischeR BetreuerIn)
Format:	UnknownFormat
Sprache:	eng
Veröffentlicht:	Potsdam 2021
Schlagworte:	Hochschulschrift > Proteine > Muscheln > Dihydrooxazole > Polymerisation > Beschichten > Copolymerisation > Brenzcatechin
Online Zugang:	Inhaltsverzeichnis
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Beschreibung
Zusammenfassung:	Dissertation, Universität Potsdam, 2022 Nature developed countless systems for many applications. In maritime environments, several organisms established extra-ordinary mechanisms to attach to surfaces. Over the past years, the scientific interest to employ those mechanisms for coatings and long-lasting adhering materials gained significant attention. This work describes the synthesis of bio-inspired adsorbing copoly(2-oxazoline)s for surface coatings with protein repelling effects, mimicking mussel glue proteins. From a set of methoxy substituted phenyl, benzyl, and cinnamyl acids, 2-oxazoline monomers were synthesized. All synthesized 2-oxazolines were analyzed by FT-IR spectroscopy, NMR spectroscopy, and EI mass spectrometry. With those newly synthesized 2-oxazoline monomers and 2-ethyl-2-oxazoline, kinetic studies concerning homo- and copolymerization in a microwave reactor were conducted. The success of the polymerization reactions was demonstrated by FT-IR spectroscopy, NMR spectroscopy, MALDI-TOF mass spectrometry, and size exclusion chromatography (SEC). [...]
Beschreibung:	iii, 224 Seiten Illustrationen, Diagramme